66/100 as a percentage is 66.00%. This fraction represents a little more than half, and when we write it as a percent it shows exactly how many parts out of 100 it covers.
The fraction 66/100 is already close to a whole number, so the percent form looks clean and easy to read. It tells you that for every 100 parts, 66 are taken.
When you see 66.00%, you can quickly understand that the value is just a bit higher than 65% and lower than 70%. This makes it simple to compare with other percentages.
Using the percent version is handy in everyday situations like grading, budgeting, or measuring success rates, because most people think in terms of "out of 100".